We did an initial investigation on the correlation between the Carbon Nanotube (CNT)/polymer composite texture from optical image and its conductive values. The optical image is processed further by so-called machine vision system to explore the specific texture of CNT filler in the matrix. The output from image processing were interpreted and assumed to be matched with the electrical properties measurement. By using CNT filler concentration of 0.6% - 1.3%, we resulted in conductivity of CNT/polymer film from 4.6x10-5-6.8x10-4S/m. Moreover these values are well corresponded with their texture quantity.